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Physico-Chemical Calculations: (English)

Physico-Chemical Calculations: (English)

          
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About the Book

This historic book may have numerous typos and missing text. Purchasers can download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1912 Excerpt: ...problem is 2 litres, what weight of Fe304 is formed at equilibrium? Ans. 2-85 grams. Problem 192.--Amylene and trichloracetic acid react to form an ester according to the equation CC13. C0OH + C5H10 = CCl3. COOC5Hn. In an experiment at 100 the equilibrium mixture contained 3-846 gram-molecules amylene per litre, 0-6594 gram-molecule acid per litre, and 2-111 gram-molecules ester per litre. If we start with 1 gram-molecule acid, and 4-48 gram-molecules amylene in 638 c.c. at 100, what is the composition of the mixture at equilibrium? Ans. 0-174 gram-molecule acid, 3-654 gram-molecules amylene, and 0'826 gram-molecule ester in 638 c.c. Problem 193.--Solid NH4CN has a considerable vapourpressure at ordinary temperatures, and the vapour is practically completely dissociated into NH3 and HCN. At 11 C. the total vapour-pressure is 22-7 cms. of mercury, (a) What will be the partial pressure of HCN if solid NH4CN is allowed to sublime at 11 in a closed vessel filled with NH3 at a pressure of 32-28 cms. of mercury? (b) What will be the final total pressure? Ans. (a) 3-595 cms. Hg, (b) 39-47 cms. Hg. Problem 194.--If the volume of the vessel in the preceding problem is 1 litre, how much NH4GN will sublime? Ans. 0-00203 gram-molecule. Problem 195.--At 96 the ammonia dissociation-pressure of the compound LiC1. NH3 according to the equation LiCl. NH3 = LiC1 + NH3 is 367 mm. of mercury, and at 109-2 it is 646 mm. Calculate the heat of dissociation of the compound. Ans.-12000 cals. Problem 196.--At 2000 0., and under atmospheric pressure, carbon dioxide is 1-80 per cent, dissociated according to the equation 2C02 = 200 + O, . Calculate the equilibrium-constant for the above reaction using partial pressures (in atmospheres). Ans. 3 x 10--. Problem 197.--What is the equ...


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Product Details
  • ISBN-13: 9781152225756
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 50
  • Series Title: English
  • Weight: 109 gr
  • ISBN-10: 1152225758
  • Publisher Date: 01 May 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Spine Width: 3 mm
  • Width: 189 mm

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