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Starch derivatization: Fascinating and unique industrial opportunitiesFascinating and unique industrial opportunities

Starch derivatization: Fascinating and unique industrial opportunitiesFascinating and unique industrial opportunities

          
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About the Book

"This publication addresses the large possibilities of starch as an industrial raw material. Starch is industrially produced on a large scale, from various plants such as corn, tapioca and potato. It is renewable, ""green"" and cheap. Although the starches from these plants differ, the current application areas are the same. Besides the classical applications of starch in food products, their use as adhesives and in the paper and textile industry, new applications such as bioplastics are being developed. Currently a relatively small number of chemicals are used industrially for modification. By varying the degree of modification and the combination of different modifications a large number of products can be prepared. New possibilities are created by the use of new chemicals and the preparation of highly substituted products in non conventional solvents, such as aqueous alcohols. Using newly developed enzymes also increases the scope of applications. This book describes a number of new developments and addresses topics such as: - Relation between granular structure and derivatization - Derivatization in aqueous alcohol - New starch esters - Use of spacers in derivatization - Enzymatic derivatization The book is meant for the (industrial) starch researcher as well as for everyone else interested in the derivatization and application of polysaccharides and natural polymers."

Table of Contents:
Fascinating and unique industrial opportunities 3; Preface 7; The starch granule, effects of crystallinity and surface on derivatization 13; Structural elements, surface layers 14; Channels, pores and voids 16; Changing the surface, active surface spots 18; Surface substitution 19; Hydrolysis 21; Ghosts 21; Substituent distribution 21; Drying of starch, never dried starch 23; Derivatization in aqueous alcohols 27; A: native starch 27; Carboxymethylation 28; Cationization 29; Hydroxyethylation 29; Esterification 29; Cross-linking 29; Hydrophobic starch 29; Hydrolysis 30; Oxidation 31; Physical modification 31; Enzymatic conversion 32; Derivatization in aqueous alcohols 33; B: Pre-cooked starches 33; Preparation of cold water soluble starch slurries in aqueous alcohol 34; Chemical derivatization 34; Physical modification 34; Reactions at low temperature 35. Application of granule swelling inhibitors in derivatization 37; Swelling inhibitors, inorganic salts 37; Side effects 39; Organic swelling inhibitors 39; Amylose inclusion complexes 41; Synergistic effects 47; Carbohydrate oxidation with oxygen, varieties on the Spengler- and Pfannenstiel reactions 51; Spacers 59; The phosphate group in sugar- and starch phosphates as nucleophile 63; Acetoacetylation of starch and cellulose 67; Cellulose 69; Polyvinylalcohol and other alcohols 70; Derivatization with mixed anhydrides 73; Derivatization with alkyl sulfates 81; Cyanamide, a reagent with potential 89; Urea and starch derivatization 93; Starch and sugar derivatives with amidoxime and hydroxamic acid groups 99; Ester migration in carbohydrates 105; Unusual carbohydrate esters, ferulic-, gallic- and lactic acid esters 109; Ferulic acid esters 109; Gallic acid esters 112; Lactic acid esters 116; Super absorbents based on starch 121. The application of enzymes involved in starch derivatization:; Some recent developments 129; Application of hydrolases 129; Application of transferases 133; Application of lyases 137; Application of oxidoreductases 137; Application of isomerases 139; The application of peroxidases 143; General 143; Cross-linking of pectins by peroxidase action 145; Enzymatic cross-linking of proteins 145; Peroxidases for the improvement of bread 146; Removing phenol with horseradish 147; Improve your washing with fungal enzymes 147; Lignin peroxidase and bio-pulping 148; The application of haloperoxidases for the preparation of glucosone 149; Oxidation of alcohols with chloroperoxidases 149; Derivatisation of starch with peroxidases 149; Some interesting oligosaccharides 153; Raffinose 153; Lactosucrose 155; Oligosaccharide phosphates 156; Various 157.


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Product Details
  • ISBN-13: 9789076998602
  • Publisher: Wageningen Academic Publishers
  • Publisher Imprint: Wageningen Academic Publishers
  • Depth: 6
  • Language: English
  • Returnable: 03
  • Sub Title: Fascinating and unique industrial opportunitiesFascinating and unique industrial opportunities
  • Width: 170 mm
  • ISBN-10: 9076998604
  • Publisher Date: 14 Apr 2005
  • Binding: Paperback
  • Height: 240 mm
  • No of Pages: 158
  • Returnable: Y
  • Weight: 263 gr


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