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Structure and Properties of Glassy Polymers: (710 ACS Symposium Series)

Structure and Properties of Glassy Polymers: (710 ACS Symposium Series)

          
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About the Book

In twenty-nine chapters by leading authorities, Structure and Properties of Glassy Polymers provides readers with comprehensive coverage of basic and applied research on glass polymers as well as a wealth of information on current topics such as molecular modelling, characterization, polymer glasses in confined spaces, and conducting glass polymers. The characterization techniques presented include temperature-modulated differential scanning calorimetry, dielectric loss spectroscopy, photochemical hole burning, positron annihilation lifetime spectroscopy, and transient current generation.

Table of Contents:
1. The structure and properties of glassy polymers: an overview ; PHYSICS OF GLASSY POLYMERS ; 2. The use of configurational entropy to derive the kinetic properties of polymer glasses ; 3. Entropy, landscapes, and fragility in liquids and polymers, and the detlaCp problem ; 4. Dynamic properties of polymer melts above the glass transition: monte carlo results ; 5. The thermal glass transition beyond the time trap ; 6. Dynamic monte carlo simulation and dielectric measurements of the effect of pre size on glass transition temperature and the state of the glass ; 7. Temperature-modulated calorimetry of the frequency dependence on the glass transition of poly(ethylene terephthlate) and polystyrene ; MOLECULAR MOBILITY AND RELAXATIONS IN THE GLASSY STATE ; 8. Polymer glasses: thermodynamic and relaxational aspects ; 9. Structural relaxation and fragility of glass-forming miscible blends composed of atactic polystyrene and poly(2,6-dimethyl-1,4-phenylene oxide) ; 10. Dielectric spectroscopy of bisphenol-A polycarbonate and some of its blends ; 11. Physical ageing in PMMA investigated using positron annihilation, dielectric relaxation, and dynamic mechanical thermal analysis ; 12. Low temperature relaxation of polymers probed by photochemical hole burning ; PHYSICAL AGING ; 13. Fitting DSC heating curves for polyetherimide using a model of structural recovery ; 14. The physics of glassy polycarbonate: superposability and volume recovery ; 15. Polymer-polymer miscibility investigated by temperature modulated differential scanning calorimetry, T-m.d.s.c. ; 16. Physical ageing in PMMA investigated using positron annihilation, dielectric relaxation, and dynamic mechanical thermal analysis ; MECHANICAL PROPERTIES ; 17. Craze initiation and failure in glassy poly(ethylene terephthalate): the effects of physical aging with and without exposure to chemical environments ; 18. Transitions, properties, and molecular mobility during cure of thermosetting resins ; 19. A dynamic probe of tribological processes at metal/polymer interfaces: transient current generation ; 20. The effects of orientation by solid state processes on the amorphous regions in poly(vinyl alcohol) and high density poly(ethylene) ; TRANSPORT PROPERTIES ; 21. Free volume and transport properties of barrier and membrane polymers ; 22. The segmental motion and gas permeability of glassy polymer poly[1-(trimethylsiyl-1-propyne)] membranes ; 23. Vacancy spectroscopy of polymers using positronium ; 24. Sub-nanometer hole properties of cellulose studies by positron annihilation lifetime spectroscopy ; 25. Ionic conductivity in glassy PVOH/lithium salt systems ; 26. Oxygen transport through electrically conductive polyanilines ; 27. Xenon-129 NMR as a probe of polymer sorption sites: a new view of structure and transport ; 28. Dissolution mechanism of glassy polymers: a molecular analysis ; 29. Gas barrier and thermal properties of alkysulfonylmethyl substituted poly(oxyalkylene)s


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Product Details
  • ISBN-13: 9780841235885
  • Publisher: American Chemical Society
  • Publisher Imprint: American Chemical Society
  • Height: 236 mm
  • No of Pages: 480
  • Series Title: 710 ACS Symposium Series
  • Weight: 804 gr
  • ISBN-10: 0841235880
  • Publisher Date: 25 Feb 1999
  • Binding: Hardback
  • Language: English
  • Returnable: N
  • Spine Width: 27 mm
  • Width: 159 mm


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