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Home > A System of Instruction in Qualitative Chemical Analysis: (English)
A System of Instruction in Qualitative Chemical Analysis: (English)

A System of Instruction in Qualitative Chemical Analysis: (English)

          
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About the Book

This historic book may have numerous typos and missing text. Purchasers can usually download a free scanned copy of the original book (without typos) from the publisher. Not indexed. Not illustrated. 1855 edition. Excerpt: ...of malic acid is highly characteristic. If the experiment is made in a small spoon, pungent acid vapors of maleic acid are evolved with effervescence. If the experiment is made in a small tube, these fumes condense to crystals in the colder part of the tube. 2. Malic acid forms with most bases, salts soluble in water. The acid malate of potassa is not difficultly soluble in water. Malic acid prevents, like tartaric acid, the precipitation of sesquioxide of iron, &c., by alkalies. 3. Chloride of calcium fails to produce a precipitate in solutions of free malic acid. Even after saturation with potassa or soda no precipitate is formed. But upon boiling, a precipitate of malate of lime separates from concentrated solutions. If the precipitated malate of lime is dissolved in a very little hydrochloric acid, ammonia added to the solution, and the fluid boiled, the malate of lime separates again; but if it is dissolved in a somewhat larger quantity of hydrochloric acid, it will not reprecipitate, after addition of ammonia in excess, even upon continued boiling. Alcohol precipitates it immediately from a solution of the kind. 4. Lime-water produces no precipitate, either in solutions of free malic acid or in solutions of malates. 5. Acetate of lead throws down from solutions of malic acid and of malates, a white precipitate of Malate Of Lead (Pb O, M). The precipitation is the most complete, if the fluid is neutralized by ammonia, as the precipitate is soluble in free malic acid and acetic acid, and also in ammonia. If the fluid in which the precipitate is suspended is heated to boiling, the precipitate fuses to a mass resembling resin melted under water. This reaction is distinctly marked only when the malate of lead is tolerably pure; if it...


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Product Details
  • ISBN-13: 9781155024585
  • Publisher: Rarebooksclub.com
  • Publisher Imprint: Rarebooksclub.com
  • Height: 246 mm
  • No of Pages: 144
  • Series Title: English
  • Weight: 268 gr
  • ISBN-10: 1155024583
  • Publisher Date: 01 Oct 2012
  • Binding: Paperback
  • Language: English
  • Returnable: N
  • Spine Width: 8 mm
  • Width: 189 mm


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